钟康宝,男,博士,讲师,硕士生导师
联系方式:zhongkangbao@htu.edu.cn
教育经历:
2016/09-2023/06 重庆大学 化学 博士学位 导师:蓝宇教授
2012/09-2016/06 海南大学 高分子材料与工程 学士学位 导师:杜杰教授
工作经历:
2023/06-至今 beat365官方登录入口 化学 讲师
研究领域与兴趣:
1.计算有机化学
2.机器学习辅助的合成应用研究
代表性论文:
(1). Zhong, K.; Shan, C.; Zhu, L.; Liu, S.; Zhang, T.; Liu, F.; Shen, B.; Lan, Y.*; Bai, R.* Theoretical Study of the Addition of Cu−Carbenes to Acetylenes to Form Chiral Allenes. J. Am. Chem. Soc. 2019, 141, 5772-5780.
(2). Zhong, K.; Liu, S.; He, X.; Ni, H.; Lai, W.; Gong, W.; Shan, C.; Zhao, Z.; Lan, Y.*; Bai, R.* Oxidative Cyclopalladation Triggers the Hydroalkylation of Alkynes.Chin. Chem. Lett.2023, 34, 108339
(3). Lai, W.; Zhong, K.*; Liu, S.; Liu, S.; Chen, H.; Ni, H.; Zeng, Z.; Zhao, Z.; Lan, Y.*; Bai, R.* How Strain-Release Determines Chemoselectivity: A Mechanistic Study of Rhodium-Catalyzed Bicyclo[1.1.0]butane Activation. J. Phys. Chem. Lett.2022, 13, 7694−7701(*corresponding authors)
(4). Zhang, T.†; Zhong, K.†; Lin, Z-K.; Niu, L.; Li, Z.; Bai, R.*; Engle, K*; Lan, Y* Revised Mechanism of C(sp3)–C(sp3) Reductive Elimination from Ni(II) with the Assistance of a Z-Type Metalloligand. J. Am. Chem. Soc. 2023, 145, 2207–2218. (†co-author)
(5). Wang Q.†; Zhong, K.†; Xu H†; Li S; Zhu W; Ye F; Xu Z; Lan, Y.*; Xu L* Enantioselective Nickel-Catalyzed Si-C(sp2) Bond Activation and Migratory Insertion to Aldehydes: Reaction Scope and Mechanism ACS. Catal.2022, 12, 4571−4580. (†co-author)
(6). Shan, C.†;Zhong, K.†; Qi, X.; Xu, D.; Qu, L-B.; Bai, R.*; Lan, Y.* Long distance unconjugated agostic-assisted 1,5-H shift in a Ru-mediated Alder-ene type reaction: mechanism and stereoselectivity. Org. Chem. Front. 2018, 5, 3178-3185. (†co-author)
(7). Huo, J.†; Zhong, K.†; Xue, Y.; Lyu, M.; Ping, Y.; Ouyang, W; Liu, Z.; Lan, Y.*; Wang, J.*Ligand-Controlled Site- and Enantioselective Carbene Insertion into Carbon–Silicon Bonds of Benzosilacyclobutanes.Chem. Eur. J. 2022, 28,e202200191. († co-author)